Palladium metal nanoparticle size control through ion paired structures of [PdCl4]2− with protonated PDMAEMA

Behzad Tangeysh, Michael Fryd, Marc A. Ilies, Bradford B. Wayland

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

The mean diameter of palladium metal particles produced by citrate reduction of the (H+)n PDMAEMA/[PdCl4]2− aqueous system increases from 1.4 nm to 5.0 nm as the pH decreases from 6.3 to 3.3 and the (H+)n PDMAEMA/[PdCl4]2− species undergo conversion from a cross linked polymer network to a single chain structure.

Original languageEnglish
Pages (from-to)8955-8957
Number of pages3
JournalChemical Communications
Volume48
Issue number71
DOIs
StatePublished - Aug 8 2012

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